Adelina Sotnikova became the first Russian to win gold in the Olympic women's figure skating with a superb performance
The 17-year-old former world junior champion scored highly on the technical elements to finish with a score of 224.59.
Vancouver champion Yuna Kim of South Korea led after the short programme but had to settle for silver.
Italy's Carolina Kostner claimed the bronze medal.
Russian 15-year-old Yulia Lipnitskaya, who helped her country win team gold, finished in fifth position scoring a total of 200.57.
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